Product ID:AF777, PRESTONE ANTIFREEZE/COOLANT
MSDS Date:10/18/1999
FSC:6850
NIIN:01-252-8501
Status Code:A
MSDS Number: CLPRT

PRESTONE PRODUCTS CORP

39 OLD RIDGEBURY RD
DANBURY, CT 06810-5109
US

Emergency Phone: (800)424-9300

Info Phone: 203-731-3686/830-7865

Preparer: STAN PRUSAKOWSKI

Cage: 0CXZ7

PRESTONE PRODUCTS CORP

DANBURY, CT 06810-5109 US

Telephone: 203-731-3686/830-7865

Cage: 0CXZ7

ETHYLENE GLYCOL (AEROSOL)

CAS: 107-21-1

RTECS: KW2975000

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

DIETHYLENE GLYCOL

CAS: 111-46-6

RTECS: ID5950000

NON-HAZARDOUS INGREDIENTS WATER

CAS: 7732-18-5

RTECS: ZC0110000

LD50 LC50 Mixture:NOT PROVIDED
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:INHALATION: MAY CAUSE IRRITATION OF
NOSE AND THROAT. HIGH VAPOR CONCENTRATIONS MAY PRODUCE NAUSEA,
VOMITING, HEADACHE, DIZZINESS AND IRREGULAR EYE MOVEMENTS. SKIN
CONTACT: NO EVIDENCE OF ADVERSE EFFEC TS. EYE CONTACT: LIQUID,
VAPOR OR MIST MAY CAUSE DISCOMFORT IN THE EYE WITH PERSISTENT
CONJUNCTIVITIS. INGESTION: MAY CAUSE ABDOMINAL DISCOMFORT/PAIN, A
BITTER TASTE, NAUSEA, VOMITING, DIZZINESS, DROW SINESS, MALAISE,
BLURRING VISION, BACK PAIN, KIDNEY FAILURE. CARDIAC FAILURE,
PULMONARY EDEMA, SEVERE KIDNEY AND LIVER DAMAGE MAY ALSO OCCUR. MAY
BE FATAL. CHRONIC: CENTRAL NERVOUS SYSTEM INVOLVEMENT, SKIN
SENSITIZATION, DERMATITIS.
Explanation of Carcinogenicity:NONE OF THE COMPONENTS IN THESE PRODUCTS
IS LISTED AS A CARCINOGEN OR SUSPECTED CARCINOGEN BY IARC, NTP OR
OSHA.
Effects of Overexposure:INHALATION: HIGH VAPOR CONCENTRATIONS MAY
PRODUCE NAUSEA, VOMITING, HEADACHE DIZZINESS AND IRREGULAR EYE
MOVEMENTS. INGESTED: ABDOMINAL DISCOMFORT/PAIN, A BITTER TASTE,
NAUSEA, VOMITING, DIZZINESS, D ROWSINESS, MALAISE, BLURRING VISION,
BACK PAIN. EYE CONTACT: REDNESS, CONJUNCTIVA, DISCOMFORT.
Medical Cond Aggravated by Exposure:THE AVAILABLE TOXICOLOGICAL
INFORMATION AND A KNOWLEDGE OF THE PHYSICAL AND CHEMICAL PROPERTIES
OF THE MATERIAL SUGGEST THAT OVEREXPOSURE IS UNLIKELY TO AGGRAVATE
EXISTING MEDICAL CONDITIONS.

First Aid:INHALATION: REMOVE VICTIM TO FRESH AIR. IF BREATHING HAS
STOPPED, ADMINISTER ARTIFICIAL RESPIRATION. IF BREATHING IS
DIFFICULT, HAVE MEDICAL PERSONNEL ADMINISTER OXYGEN. GET MEDICAL
ATTENTION. SKIN: I MMEDIATELY WASH CONTACTED AREA THOROUGHLY WITH
SOAP AND WATER. IF IRRITATION PERSISTS, GET MEDICAL ATTENTION.
EYES: IMMEDIATELY FLUSH WITH LARGE AMOUNT OF WATER FOR 15 MINUTES.
GET MEDICAL ATTENTION I F IRRITATION PERSISTS. INGESTION: SEEK
IMMEDIATE MEDICAL ATTENTION. CALL POISON CONTROL CENTER. NEVER GIVE
ANYTHING BY MOUTH TO OR INDUCE VOMITING IN AN UNCONSCIOUS OR DROWSY
PERSON.

Flash Point Method:PMCC
Flash Point:=104.4C, 220.F
Autoignition Temp:Autoignition Temp Text:N/D
Lower Limits:3.2
Upper Limits:15.3
Extinguishing Media:FOR LARGE FIRES, USE ALCOHOL TYPE OR ALL-PURPOSE
FOAMS. FOR SMALL FIRES, USE WATER SPRAY, CARBON DIOXIDE OR DRY
CHEMICAL.
Fire Fighting Procedures:DO NOT SPRAY POOL FIRES DIRECTLY. COOL FIRE
EXPOSED CONTAINERS WITH WATER. FIREFIGHTERS SHOULD WEAR POSITIVE
PRESSURE SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE
CLOTHING FOR FIRES IN AREAS WHERE CHEMICALS ARE USED OR STORED.
Unusual Fire/Explosion Hazard:A SOLID STREAM OF WATER OR FOAM DIRECTED
INTO HOT, BURNING LIQUID CAN CAUSE FROTHING.

Spill Release Procedures:WEAR APPROPRIATE PROTECTIVE CLOTHING AND
EQUIPMENT. COLLECT WITH ABSORBENT MATERIAL AND PLACE IN
APPROPRIATE, LABELED CONTAINER FOR DISPOSAL OR, IF PERMITTED FLUSH
SPILL AREA WITH WATER.
Neutralizing Agent:NOT PROVIDED

Handling and Storage Precautions:DO NOT STORE IN OPENED OR UNLABELED
CONTAINERS. KEEP CONTAINERS AWAY FROM OPEN FLAMES AND EXCESSIVE
HEAT. DO NOT REUSE EMPTY CONTAINERS UNLESS PROPERLY CLEANED. USE OF
THIS PRODUCT IN ELEVATED TEMPERA TURE APPLICATIONS SHOULD BE
THOROUGHLY EVALUATED TO ASSURE SAFE OPERATIONS.
Other Precautions:DO NOT DRINK ANTIFREEZE OR SOLUTION. AVOID EYE AND
PROLONGED OR REPEATED SKIN CONTACT. AVOID BREATHING VAPORS OR
MISTS. WASH EXPOSED SKIN THOROUGHLY WITH SOAP AND WATER AFTER USE.
EMPTY CONTAINERS RET AIN PRODUCT RESIDUES AND MAY BE DANGEROUS. DO
NOT CUT, WELD, DRILL, ETC. CONTAINERS, EVEN EMPTY.

Respiratory Protection:IF THE TLV IS EXCEEDED A NIOSH APPROVED
RESPIRATOR WITH ORGANIC VAPOR CARTRIDGE AND DUST/MIST PREFILTERS OR
SUPPLIED AIR RESPIRATOR IS RECOMMENDED. EQUIPMENT SELECTION DEPENDS
ON CONTAMINANT TYPE AND CONCENTRATION. SELECT AND USE IN
ACCORDANCE WITH 29 CFR 1910.134 AND GOOD INDUSTRIAL HYGIENE
PRACTICE. FOR FIREFIGHTING, USE SELF-CONTAINED BREATHING APPARATUS.
Ventilation:USE GENERAL VENTILATION OR LOCAL EXHAUST AS REQUIRED TO
MAINTAIN EXPOSURES BELOW THE OCCUPATIONAL EXPOSURE LIMITS.
Protective Gloves:CHEMICAL RESISTANT GLOVES SUCH AS NEOPRENE OR PVC
WHERE CONTACT IS POSSIBLE.
Eye Protection:SPLASH-PROOF GOGGLES.
Other Protective Equipment:APPROPRIATE PROTECTIVE CLOTHING AS NEEDED TO
MINIMIZE SKIN CONTACT. SUITABLE WASHING AND EYE FLUSHING FACILITIES
SHOULD BE AVAILABLE IN THE WORK AREA.
Work Hygienic Practices:CONTAMINATED CLOTHING SHOULD BE REMOVED AND
LAUNDERED BEFORE RE-USE.
Supplemental Safety and Health
ABBREVIATION: N/A = NOT APPLICABLE. N/AV = NOT AVAILABLE. N/K =
UNKNOWN. N/P = NOT PROVIDED. N/R = NOT RELEVANT. N/D = NOT
DETERMINED. N/E = NOT ESTABLISHED. CNS = CENTRAL NERVOUS SYSTEM. GI
= GASTROI NTESTINAL. SCBA = SELF CONTAINED BREATHING APPARATUS.

HCC:V5
NRC/State Lic Num:NOT RELEVANT
Boiling Pt:=167.8C, 334.F
Melt/Freeze Pt:=-22.2C, -8.F
Decomp Temp:Decomp Text:NOT PROVIDED
Vapor Pres:<0.1
Vapor Density:2.1
Spec Gravity:1.12
pH:NOT DETERMINED
Viscosity:NOT DETERMINED.
Evaporation Rate & Reference:<1
Solubility in Water:COMPLETE (100%)
Appearance and Odor:YELLOW LIQUID WITH A MILD ODOR.
Percent Volatiles by Volume:NONE
Corrosion Rate:NOT PROVIDED

Stability Indicator/Materials to Avoid:YES
NORMALLY UNREACTIVE. HOWEVER, AVOID STRONG BASES AT HIGH TEMPERATURES,
STRONG ACIDS, STRONG OXIDIZING AGENTS AND MATERIALS REACTIVE WITH
HYDROXYL COMPOUNDS.
Stability Condition to Avoid:NONE KNOWN.
Hazardous Decomposition Products:BURNING MAY PRODUCE CARBON MONOXIDE
AND CARBON DIOXIDE.

Waste Disposal Methods:DISPOSE OF PRODUCT IN ACCORDANCE WITH ALL LOCAL,
STATE/PROVINCIAL AND FEDERAL REGULATIONS.

Toxicological Information:ETHYLENE GLYCOL LD50 ORAL RAT: 4700 MG/KG.
LD50 SKIN RABBIT: 9530 MG/KG. DIETHYLENE GLYCOL: LD50 ORAL RAT:
12,565 MG/KG AND LD50 SKIN RABBIT: 11890 MG/KG. ETHYLENE GLYCOL HAS
BEEN SHOWN TO PRODUCE DOS E-RELATED TERATOGENIC EFFECTS IN RATS AND
MICE WHEN GIVEN IN DRINKING WATER AT HIGH CONCENTRATIONS OR DOSES.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ecological:ETHYLENE GLYCOL: LC50 GOLDFISH: 5,000 MG/L/24 HR, AT 20C
STATIC CONDITIONS. TOXICITY THRESHOLD: BACTERIAL (PSEUDOMONAS
PUTIDA): 10,000 MG/L; PROTOZOA: >10,000 MG/L; ALGAE: 2,000 MG/L;
GREEN ALGAE: >10 ,000 MG/L.

Transport Information:DOT HAZARD CLASSIFICATION: NONE. IMDG: NOT
REGULATED. NOTE IF BULK SHIPMENT IS INVOLVED, THE FOLLOWING
INFORMATION APPLIES: US DOT PROPER SHIPPING NAME: ENVIRONMENTALLY
HAZARDOUS SUBSTANCE, LIQUID, N. O.S. (ETHYLENE GLYCOL), 9, UN3082.

SARA Title III Information:EPA SARA 311/312: HAZARD CLASSIFICATION:
ACUTE HEALTH AND CHRONIC HEALTH. EPA SARA 313: THIS PRODUCT
CONTAINS THE FOLLOWING CHEMICALS SUBJECT TO ANNUAL RELEASE
REPORTING REQUIREMENTS UNDER SARA TITLE III, SECTION 313 (40 CFR
372): ETHYLENE GLYCOL, CAS# 107-21-1, 80-96%. CERCLA SECTION 103:
SPILLS OF THIS PRODUCT OVER THE RQ (REPORTABLE QUANTITY) MUST BE
REPORTED TO THE NATIONAL RESPONSE CENTER. TH E RQ FOR THIS PRODUCT,
BASED ON THE RQ FOR ETHYLENE GLYCOL (96% MAXIMUM) OF 5,000 LBS, IS
5,208 LBS. MANY STATES HAVE MORE STRINGENT RELEASE REPORTING
REQUIREMENTS. REPORT SPILLS REQUIRED UNDER FEDERA L, STATE, AND
LOCAL REGULATIONS.
Federal Regulatory Information:EPA TSCA INVENTORY: ALL OF THE
COMPONENTS OF THIS MATERIAL ARE LISTED ON THE TOXIC SUBSTANCE
CONTROL ACT (TSCA) CHEMICAL SUBSTANCES INVENTORY.
State Regulatory Information:CALIFORNIA PROPOSITION 65: THIS PRODUCT
MAY CONTAIN THE FOLLOWING SUBSTANCES KNOWN TO THE STATE OF
CALIFORNIA TO CAUSE CANCER AND/OR REPRODUCTIVE HARM: 1,4-DIOXANE
(TRACE AMOUNT).